Starch Derivatives: An overview of the multifaceted industrial applications
Chemical
Modifications of Starch
Starch is chemically modified through various processes to enhance or introduce
new properties for industrial applications. Common chemical modifications
include oxidation, esterification and etherification. Oxidized starch is
produced by treating starch with hypochlorite or peroxide under controlled
conditions. This increases the hydrophilicity and viscosity of starch.
Esterified starch is made by esterifying starch with organic acids or anhydrides.
This process increases the thermal properties and shelf life of starch.
Etherified starch involves treating starch with alkyl halides which increases
its solubility in cold water and organic solvents while also reducing
viscosity.
Uses of Modified Starches
Modified starches have replaced native starches in many applications due to
their superior functional properties. Starch
Derivatives Esterified starches
find widespread use as stabilizers and thickeners in the food industry. They
are used to manufacture processed foods, desserts, soups and sauces. Oxidized
starch is used as a stabilizer in canned foods, baked products and frozen
foods. It helps maintain texture, prevent separation and reduces oil
absorption. Etherified starch is utilized as a tablet binder and disintegrant
in pharmaceuticals. It also serves as a viscosity increasing agent and
stabillizer in cosmetics and personal care products.
In non-food industries, modified starches are employed as binders, thickeners
and coatings. Cationic starch is employed in paper manufacturing as a dry and
wet end adhesive. It improves paper strength, surface sizing and runnability.
Carboxymethyl starch is utilized in the textile industry as a finishing agent
and in ceramic industries as a binder. Hydroxyethyl starch finds use in mining
and drilling industries as a viscosity modifier for bentonite clay suspension.
Alkylated starches are used in the oil drilling industry as bore-hole
stabilizers.
Applications of Starch Derivatives
Despite the advantages of modified starches, native starches continue to be
preferred for certain applications owing to factors like cost and stability.
Corn starch and potato starch are commonly used as thickening and binding
agents in food products. They are widely used in soups, sauces, puddings, meat
products, baked goods and snacks. Native starches also act as stabilizers to
prevent food items from crystallizing or settling. Tapioca starch extracted
from cassava roots adds texture to bakery products like buns and bread. Wheat
starch and rice starches find applications as binders in solid oral dosage
forms. Maize and potato starches are employed in coating tablets to improve
appearance and flow ability.
Cornstarch provides the desirable texture to commonly consumed western cuisines
like gravy. It is also used as an anti-caking agent in powdered foods. Wheat
starch is used to modify viscosity in products like ice creams. Cassava starch
serves as a thickening agent and stabilizer in commercial soups. Arrowroot
starch extracted from arrowroot plants acts as a thickener for glazes and
sauces. Sago starch obtained from sago palms is used in syrups, confectionery
and desserts preparation. Potato starch is added as a texture modifier and
thickener in commercial sauces and processed cheeses.
Prospects
The global starch market was valued at over $70 billion in 2020 and is
projected to exhibit steady growth over the next decade. Developing regions
like Asia Pacific and Latin America will drive much of the incremental gains
led by increased consumption of foods and Personal care products. Growth
opportunities lie in developing specialized native and modified starches for
niche industrial applications in areas like bioplastics, pharmaceutical
binders, oil drilling and eco-friendly textiles. Production of high purity
starches using advanced extraction techniques will also spur demand. With novel
applications emerging across diverse end use sectors, starch derivatives are
poised to retain their relevance as versatile industrial raw materials in the
chemical industry.
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